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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '76b2e05ecd2ad0b07f0447833c4e507443cd2fade12a6d50f584a1bac219888e' 
  AND token = 'qjjXPhPmnrL+RHjdOUMHtDFs7uBwyBeUNFgd3ad+fbA=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00024

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}